ChemInform Abstract: Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene‐Linked Pyrrolyl Rare Earth Metal Amido Complexes.
Abstract:New dinuclear rare earth metal amido complex SAC bearing methylene‐linked pyrrolylamido ligands is effectively used for hydrophosphonylations of aromatic and aliphatic aldehydes (I) whereas, complex YPC gives better results for unactivated aliphatic, (hetero)aromatic ketones (IV).
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