ChemInform Abstract: Generation of C6S6 and Its Radical Anion and Cation in the Gas Phase.

Suelzle, Detlev; Beye, N.; Fanghaenel, E.; Schwarz, Helmut

doi:10.1002/chin.199008036

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2003

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“…11 Group VIa elements are particularly efficient capping agents. [12][13][14] Small even-and odd-numbered polycarbon disulfides SC n S (n ) 2-6) were generated using electron impact ionization of 2H,5H,8H-benzo[1,2-d:3,4-d′:5,6-d′′]tri(1,3-dithiol)-2,5,8-trion and studied by collisional activation. 15 Small (n ) 1-5) asymmetric and symmetric carbon sulfur clusters have been produced in an argon matrix.…”

Section: Introductionmentioning

confidence: 99%

SC_nS Linear Chain Production by Direct Laser Ablation

Burnin

BelBruno

2003

J. Phys. Chem. A

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Cumulenic polycarbons SC n S (n = 2−27) were generated by laser ablation of mixtures of elemental carbon and sulfur. The resulting molecules were analyzed in a time-of-flight mass spectrometer. The spectra exhibited ideal odd/even intensity alternation attributed to their relative stability and the formation mechanism of the clusters. The structures and energies of the neutral and charged carbon chains capped with two sulfur atoms were also studied by density functional theory. The computational results were consistent with the experimental observations. Evidence of sulfur poisoning of fullerene formation was observed and explained in terms of one of the existing models for fullerene formation and growth.

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