ChemInform Abstract: First Total Synthesis of the Pandanus Alkaloids, Pandamarilactam‐3Y and ‐3X.

Abstract

First Total Synthesis of the Pandanus Alkaloids, Pandamarilactam-3Y and -3X.-Aldol-type condensation of aldehyde (IV) with the siloxyfuran (V) followed by β-elimination of TbsOH leads to a total synthesis of pandamarilactam-3Y (VI) and -3X (VII). -(TAKAYAMA, HIROMITSU;