ChemInform Abstract: Fate of a Giant {Mo₇₂Fe₃₀}‐Type Polyoxometalate Cluster in an Aqueous Solution at Higher Temperature: Understanding Related Keplerate Chemistry, from Molecule to Material.

Abstract

precipitate. Approximately 50% of the {Mo 72 Fe 30 } Keplerate are converted while 50% remain in solution. The stability of the giant icosahedral {Mo 72 Fe 30 } cluster is discussed in terms of a linker-pentagon complementary relationship. -(MEKALA, R.; SUPRIYA*, S.; DAS, S. K.; Inorg. Chem. 52 (2013) 17, 9708-9710, http://dx.