ChemInform Abstract: Exploiting the gem‐Disubstitution Effect in FcPHOX and HetPHOX P,N Ligands: Synthesis and Applications in Pd‐Catalyzed Intermolecular Heck Reactions.

Abstract

Exploiting the gem-Disubstitution Effect in FcPHOX and HetPHOX P,N Ligands: Synthesis and Applications in Pd-Catalyzed Intermolecular Heck Reactions. -The asymmetric Pd-catalyzed arylation of dihydrofurans is achieved under microwave irradiation and in the presence of chiral oxazoline ligands. -(MCCARTNEY, D.; NOTTINGHAM, C.; MUELLER-BUNZ, H.; GUIRY*, P. J.; J. Org. Chem. 80 (2015) 20, 10151-10162, http://dx.doi.org/10.1021/acs.joc.5b01764 ; Cent. Synth. Chem. Biol., Univ. Coll., Dublin 4, Ire.; Eng.) -F. Berndt