ChemInform Abstract: Ene Approach for Concurrent Control Over the Chiral Centres at C‐20 and C‐22 of Steroid Side Chains: A Highly Stereocontrolled Synthesis of (20S,22R)‐(erythro)‐22‐Hydroxy‐23,24‐acetylenic Steroid Side Chains.

MIKAMI, K.; Loh, Teck Peng; Nakai, Tadashi

doi:10.1002/chin.198919277

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ChemInform

1989

DOI: 10.1002/chin.198919277

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ChemInform Abstract: Ene Approach for Concurrent Control Over the Chiral Centres at C‐20 and C‐22 of Steroid Side Chains: A Highly Stereocontrolled Synthesis of (20S,22R)‐(erythro)‐22‐Hydroxy‐23,24‐acetylenic Steroid Side Chains.

K. MIKAMI¹,

Teck Peng Loh²,

Tadashi Nakai³

Abstract: The steroidal alkene (I) is coupled with the acetylenic aldehydes (IIa) ‐ (IIc), forming the erythro‐alcohols (III) as the main products.

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ChemInform Abstract: Ene Approach for Concurrent Control Over the Chiral Centres at C‐20 and C‐22 of Steroid Side Chains: A Highly Stereocontrolled Synthesis of (20S,22R)‐(erythro)‐22‐Hydroxy‐23,24‐acetylenic Steroid Side Chains.

Abstract: The steroidal alkene (I) is coupled with the acetylenic aldehydes (IIa) ‐ (IIc), forming the erythro‐alcohols (III) as the main products.

Cited by 0 publications

References 1 publication

No citations

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