Chemischer Informationsdienst
 1979
DOI: 10.1002/chin.197931146
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ChemInform Abstract: DOMINANT DOUBLE ROTATION IN THE THERMALLY INDUCED 1,2,4‐TRIMETHYLSPIROPENTANE GEOMETRIC ISOMERIZATION

Joseph J. Gajewski1,
Robert J. Weber2,
Ming Jing Chang3

Abstract: Die Isomerisierungen z.B. des Spiropentans (I) zu seinen Isomeren (II) und (III) erfolgen bei 561.7 K als Reaktionen 1. Ordnung unter reversibler C1‐C2‐Bindungsspaltung, wobei die bevorzugten doppelten Inversionen etwa ebenso schnell sind wie zwei einzelne Inversionen.

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