ChemInform Abstract: DISSYMMETRIC CHROMOPHORES. 7. OPTICAL ACTIVITY OF CONJUGATED CISOID DIENES: EXPERIMENTAL‐THEORETICAL STUDY OF 5‐ALKYL‐1,3‐CYCLOHEXADIENES
Abstract:(+)‐Pulegon läßt sich durch Retroaldolisierung stereoselektiv in das (3R)‐Methyl‐cyclohexanon umwandeln und zum Derivat (Ia) bromieren, dessen Tosylhydrazon (Ib) durch Dehydrobromierung in das Azin (II) übergeht und mit Triethylamin zum Hydrazon (III) isomerisiert.
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