ChemInform Abstract: Directed ortho Metalation and Suzuki—Miyaura Cross‐Coupling Connections: Regiospecific Synthesis of all Isomeric Chlorodihydroxybiphenyls for Microbial Degradation Studies of PCBs.
Abstract:2000 polyphenyl derivatives polyphenyl derivatives Q 0700 21 -098 Directed ortho Metalation and Suzuki-Miyaura Cross-Coupling Connections: Regiospecific Synthesis of all Isomeric Chlorodihydroxybiphenyls for Microbial Degradation Studies of PCBs. -The synthesis of six isomeric chlorodihydroxybiphenyls, e.g. (IVb), (IX), and (XIV), is carried out by combining the directed ortho metalation with the Pd-catalyzed Suzuki-Miyaura cross-coupling reaction. The key conceptual features include new strategies of oxygen-d… Show more
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