ChemInform Abstract: Direct Metalation of 1,3,5,7‐Tetranitrocubane with Amides of Tin and Lead. Preparation and Chemistry of o‐Nitrostannanes and o‐Nitroplumbanes in the Cubyl Series.
Abstract:bridged compoundsbridged compounds Q 0060
-092Direct Metalation of 1,3,5,7-Tetranitrocubane with Amides of Tin and Lead.Preparation and Chemistry of o-Nitrostannanes and o-Nitroplumbanes in the Cubyl Series.-Metalation of tetranitrocubane (I) generates easily isolable and stable mono-to tetrasubstituted organometallic derivatives depending on the ratio of (I) to the metal amides used. In the case of bulkier (diethylamino)tributylstannanes, metalation of (I) stops after the second metalation step and is slower.… Show more
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