ChemInform Abstract: DIE SYNTH. VON BETA‐(TERT.‐BUTYLPEROXY)‐VINYLPHOSPHONSAEUREDICHLORIDEN

Abstract

Die Peroxide (I) bilden mit Phosphorpentachlorid Komplexe, die durch Behand lung mit Schwefeldioxid zu den Phosphonsäuredichloriden (II) zersetzt werden.

Chemistry of organophosphorus compounds containing the peroxide bond

“…41,42 An alternative method to symmetric dialkyl phosphonates 32 was reported by Shreibert et al. 43 The reaction of l,l-bis(fer£-butylperoxy)ethane could not be analyzed quantitatively for their "active" oxygen content and thus were characterized through their derivatives, i.e., their dibutyl phosphonate ester 40 and the bromomethoxy derivative 41. Subse- quently,41 the class of compounds 32 was expanded to include the unsaturated phosphonates containing the peroxy moiety shown in Table III.…”