ChemInform Abstract: Diastereoselective Manipulations of Bicyclo[m.1.0]alkane Derivatives. Part 5. α′‐Alkylations of Bicyclo[m.1.0]alkan‐2‐ones.

Abstract

Diastereoselective Manipulations of Bicyclo[m.1.0]alkane Derivatives. Part 5. α'-Alkylations of Bicyclo[m.1.0]alkan-2-ones. -Under kinetically controlled conditions bicyclo[m.1.0]alkan-2-ones undergo α'-alkylation with high diastereoselectivity, except for the derivatives (IX) and (XI). -(MASH, E. A.; BARON, J. A.; GREGG, T. M.; NIMKAR, S. K.; Tetrahedron 54 (1998) 12, 2669-2682; Dep. Chem., Univ. Ariz., Tucson, AZ 85721, USA; EN)