ChemInform Abstract: Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc—Pyridine Catalysis.

Tsuchimoto, Teruhisa; Fujii, Masakazu; Iketani, Yoshihiko; Sekine, Masaru

doi:10.1002/chin.201315184

ChemInform

2013

DOI: 10.1002/chin.201315184

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ChemInform Abstract: Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc—Pyridine Catalysis.

Teruhisa Tsuchimoto

Masakazu Fujii

Yoshihiko Iketani

et al.

Abstract: Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc-Pyridine Catalysis. -First time, alkynylsilanes are synthesized in excellent yields by dehydrogenative silylation of terminal alkynes with hydrosilanes. The new method is applicable to a wide range of substrates with high functional group tolerance. Even multiple dehydrogenative silylations are observed with different hydrosilanes. -(TSUCHIMOTO*, T.; FUJII, M.; IKETANI, Y.; SEKINE, M.; Adv. Synth. Catal. 354 (2012) 16, 2959-2964, http:… Show more

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