ChemInform Abstract: Cyclodisilazane Cations ‐ Synthesis and Crystal Structure.

Abstract

207 ChemInform Abstract On heating equimolar amounts of the disilazane (I) and Al2Cl6 in n-hexane/CH2Cl2, the mono-and the diprotonated products (II) and (III) are formed. They are characterized by NMR (29Si, 15N, 1H) spectral data and an X-ray structural analysis of (III) (space group C2/c, Z=4).

Crystal structures of [N(C4H9)4][NbCl4OAlCl3] and [N(C3H7)4][NbCl6]

“…The educts [N(C 4 H 9 ) 4 ]Cl, NbCl 5 6 ] 2 were mixed in equimolar amounts in a glove box. The educts [N(C 4 H 9 ) 4 ]Cl, NbCl 5 6 ] 2 were mixed in equimolar amounts in a glove box.…”