ChemInform Abstract: CYANOHALOMETHYLIDENETRIPHENYLPHOSPHORANES

Tronchet, J. M. J.; Martin, Olivier R.

doi:10.1002/chin.197945274

Chemischer Informationsdienst

1979

DOI: 10.1002/chin.197945274

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ChemInform Abstract: CYANOHALOMETHYLIDENETRIPHENYLPHOSPHORANES

J. M. J. Tronchet¹,

Olivier R. Martin²

Abstract: Die Reaktion des Phosphorans I (Ia) mit tert.‐Butylhypochlorit in CH2Cl2 bei ‐70°C unter N2 liefert die chlorsubstituierten Verbindungen (Ib), während die übrigen Produkte (Ib) durch Umsetzung von Cyanomethyltriphenylphosphoniumchlorid mit Brom bzw. Iod in CH2Cl2 in Gegenwart von Triethylamin erhalten wurden.

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ChemInform Abstract: CYANOHALOMETHYLIDENETRIPHENYLPHOSPHORANES

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