ChemInform Abstract: Crystal Structure of Pentapotassium Dihydrogen Nonavanadato(V)platinate(IV) Nonahydrate.

Abstract

Crystal Structure of Pentapotassium Dihydrogen Nonavanadato(V)platinate(IV) Nonahydrate. -K 5[H2PtV9O28]·9H2O crystallizes in the triclinic space group P1 with Z = 2 (single crystal XRD). The heteropolyanions form inversion-generated dimers, {[H 2PtV9O28]2} 10-, held together by 2-O-H···2-O and 2-O-H···3-O hydrogen bonds. -(JOO, H.-C.; LEE*, U.; Acta Crystallogr., Sect. E: Struct. Rep. Online 71 (2015) 6, 647-649, http://dx.doi.org/10.1107/S2056989015009135 ; Dep. Chem., Pukyong Natl. Univ., Busan 608-737, S. Korea; Eng.) -J. Schramke 35-005