ChemInform Abstract: Crystal Structure and Spectroscopic Characterization of CsV(SO4)2. Evidence for an Electronic Raman Transition.

Abstract

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Stoichiometry, Vibrational Modes, and Structure of Niobium(V) Oxosulfato Complexes in the Molten Nb2O5−K2S2O7−K2SO4 System Studied by Raman Spectroscopy

“…13 Moreover, a comprehensive review on the coordination chemistry of niobium is available. 14 Much more information is available on the chemistry and structure of crystalline vanadium sulfato and oxosulfato complexes [15][16][17][18][19][20][21][22] that are recognized as deactivation products of the sulfuric acid catalyst. 4,23 Crystalline oxosulfato complexes of W VI and Mo VI have also been synthesixed by precipitation from molten mixtures of WO 3 and MoO 3 dissolved in M 2 S 2 O 7 -M 2 SO 4 (M ) alkali) melts.…”