ChemInform Abstract: CONTRIBUTIONS TO THE CHEMISTRY OF TRANSITION METAL ALKYL COMPOUNDS. XXI. EXPERIMENTS FOR THE ALKYLATION OF VANADIUM(IV) CHLORIDE AND VANADIUM OXIDE TRICHLORIDE
Abstract:Bei der Reaktion von VCl4 mit Dimethyl‐ bzw. Diäthylzink in n‐Hexan bei ‐50°C entstehen keine Organovanadinverbindungen, sondern abhängig vom Molverhältnis der Ausgangsstoffe verschiedene Komplexe von VCl3, VCI, und Methylvanadindichlorid mit Dialkylzink, Alkylzink‐ Chlorid oder Zinkchlorid.
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