ChemInform Abstract: Contributions to the Chemistry of Boron. Part 236. In Quest of New and Stable Bis(organyloxy)boranes (RO)2BH for Catalytic Hydroboration.

Abstract

1997organo-boron compounds, nonmetal heterocycles organo-boron compounds, nonmetal heterocycles S 0047 -199Contributions to the Chemistry of Boron. Part 236. In Quest of New and Stable Bis(organyloxy)boranes (RO)2BH for Catalytic Hydroboration.-The title compounds are tested quantitatively in the transition metal catalyzed hydroboration of cyclopentene and the dioxaborinane. Here, ( VIII) shows to be superior to the 1,3,2-dioxaborolanes (VI) and (XIV). -(LANG, A.; NOETH, H.; THOMANN-ALBACH, M.; Chem. Ber./Recl. 130 (1997) 3, 363-369; Inst. Inorg.