ChemInform Abstract: Chiral Substituted 3‐Formylfurans from Carbohydrates: An Expedient Route via N‐Bromosuccinimide (NBS)‐Mediated Electrophilic Cyclization.
Abstract:Chiral Substituted 3-Formylfurans from Carbohydrates: An Expedient Route via N-Bromosuccinimide (NBS)-Mediated Electrophilic Cyclization. -The efficient and general method for the synthesis of the title furans involves a Heck coupling between substituted iodoenones and olefins followed by NBS-mediated electrophilic cyclization using H 2O as a nucleophile. The cyclization reactions of Heck products containing unactivated olefines lead only to traces of the desired products. -(MAL, K.; KAUR, A.; DAS*, I.; Asian … Show more
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