ChemInform Abstract: CHEMISTRY OF TRANSITION METAL ALKYL COMPOUNDS. XXIV. PREPARATION AND PROPERTIES OF TETRABENZYL MOLYBDENUM AND TETRABENZYL URANIUM

Thiele, K.‐H.; Opitz, Robert; Koehler, Eduardo Giuliani

doi:10.1002/chin.197811282

Chemischer Informationsdienst

1978

DOI: 10.1002/chin.197811282

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ChemInform Abstract: CHEMISTRY OF TRANSITION METAL ALKYL COMPOUNDS. XXIV. PREPARATION AND PROPERTIES OF TETRABENZYL MOLYBDENUM AND TETRABENZYL URANIUM

K.‐H. Thiele¹,

Robert Opitz²,

Eduardo Giuliani Koehler³

Abstract: Das bei Raumtemp. beständige, jedoch hydrolyse‐ und luftempfindliche Tetrabenzyl‐Mo (I) wird durch Umsetzung von Mo(IV)chlorid‐bis‐[THF] mit Dibenzyl‐Mg in Ether bei ‐20°C gebildet, als diamagnetische Kristalle isoliert und NMR‐spektroskopisch charakterisiert.

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ChemInform Abstract: CHEMISTRY OF TRANSITION METAL ALKYL COMPOUNDS. XXIV. PREPARATION AND PROPERTIES OF TETRABENZYL MOLYBDENUM AND TETRABENZYL URANIUM

Abstract: Das bei Raumtemp. beständige, jedoch hydrolyse‐ und luftempfindliche Tetrabenzyl‐Mo (I) wird durch Umsetzung von Mo(IV)chlorid‐bis‐[THF] mit Dibenzyl‐Mg in Ether bei ‐20°C gebildet, als diamagnetische Kristalle isoliert und NMR‐spektroskopisch charakterisiert.

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