1986
DOI: 10.1002/chin.198617366
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ChemInform Abstract: Chemistry of Opium Alkaloids. Part 21. Scission of the Epoxy Ring in 4,5α‐Epoxymorphinans: A Convenient Synthesis of β‐Dihydrothebaine, 6‐Demethoxy‐β‐di‐ hydrothebaine and Desoxycodeine‐A.

Abstract: The reductive epoxy ring opening of thebaine (Ia) and 6‐demethoxythebaine (Ib) affords exclusively the title compounds (IIa) and (IIb), respectively.

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