ChemInform Abstract: Carbometalation of α,ω‐Dienes and Olefins Catalyzed by Zirconocenes.

Abstract

reactions of organo-metal compounds reactions of organo-metal compounds O 0350 -096Carbometalation of α,ω-Dienes and Olefins Catalyzed by Zirconocenes.-A cyclocarbometalation of diolefins and carbometalation of olefins with AlMe3 in the presence of a metallocene catalyst are presented which give after oxidation with dry air alcohols in good yields. - (SHAUGHNESSY, K. H.; WAYMOUTH, R. M.; J. Am. Chem. Soc. 117 (1995) 21, 5873-5874; Dep. Chem., Univ., CA 94305, USA; EN)