ChemInform Abstract: C—C Bond Formation from Alcohols and Malonate Half Esters Using Borrowing Hydrogen Methodology.

Abstract

Carboxylic acid esters Q 0530 C-C Bond Formation from Alcohols and Malonate Half Esters Using Borrowing Hydrogen Methodology. -Alcohols are successfully converted into doubly homologated esters using a decarboxylative Knoevenagel reaction on the intermediate aldehyde. -(PRIDMORE, S. J.; WILLIAMS*, J. M. J.; Tetrahedron Lett. 49 (2008) 52, 7413-7415; Dep. Chem., Univ. Bath, Bath BA2 7AY, UK; Eng.) -Mais 14-086