ChemInform Abstract: BIOMIMETIC POLYENE CYCLIZATIONS. PARTICIPATION OF THE PHENYLACETYLENIC GROUP AS A TERMINATOR AND THE FORMATION OF C/D CIS STEROIDAL PRODUCTS
Abstract:Ausgehend vom Acetylen (I) wird über die Stufen (IIa), (IIb), (III), (IVa) und (IVb) der Aldehyd (V) synthetisiert, der sich mit dem bekannten Wittigreagenz (VI) zum Diketal (VIUv umsetzt.
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