ChemInform Abstract: BICYCLOANNULATION. IV. CARBON ATOM INSERTION: A ONE‐STEP SYNTHESIS OF TRICYCLO(3.2.1.02,7)OCTANES AND TRICYCLO(4.1.0.02,7)HEPTANES FROM CYCLOHEXENES

Cory, Robert M.; Burton, Lester P. J.; Pecherle, R. G.

doi:10.1002/chin.198009199

Chemischer Informationsdienst

1980

DOI: 10.1002/chin.198009199

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ChemInform Abstract: BICYCLOANNULATION. IV. CARBON ATOM INSERTION: A ONE‐STEP SYNTHESIS OF TRICYCLO(3.2.1.02,7)OCTANES AND TRICYCLO(4.1.0.02,7)HEPTANES FROM CYCLOHEXENES

Robert M. Cory¹,

Lester P. J. Burton²,

R. G. Pecherle³

Abstract: Aus dem Cyclohexen (I) entsteht unter Phasen‐Transfer‐Bedingungen mit Tetrabrommethan (II) das Carbenaddukt (III),das mit Methyllithium in ein Gemisch der beiden Bicyclobutane (IV) und (V) umgewandelt wird.

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ChemInform Abstract: BICYCLOANNULATION. IV. CARBON ATOM INSERTION: A ONE‐STEP SYNTHESIS OF TRICYCLO(3.2.1.02,7)OCTANES AND TRICYCLO(4.1.0.02,7)HEPTANES FROM CYCLOHEXENES

Abstract: Aus dem Cyclohexen (I) entsteht unter Phasen‐Transfer‐Bedingungen mit Tetrabrommethan (II) das Carbenaddukt (III),das mit Methyllithium in ein Gemisch der beiden Bicyclobutane (IV) und (V) umgewandelt wird.

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