ChemInform Abstract: BENZANNELATED ANNULENES. II. THE SYNTHESIS OF TRANS‐12B,12C‐DIMETHYL‐12B,12C‐DIHYDROBENZO(E)PYRENE. AN INDICATION OF THE EXCEPTIONAL AROMATICITY OF THE 15,16‐DIMETHYLDIHYDROPYRENE SYSTEM
Abstract:Umsetzen des Dibromids (I) in verdünnter Lösung mit Na‐sulfid gibt ein chromatographisch auftrennbares Gemisch etwa gleicher Teile des syn‐ (IIb) und des anti‐Thiacylophans (IIa), aus dem in einer bekannten Reaktionsfolge durch Umlagerung und Eliminierung die Titelverbindung (III) erhältlich ist.
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