ChemInform Abstract: Asymmetric Reductive Aldol‐Type Reaction with Carbonyl Compounds Using Dialkyl Tartrate as a Chiral Ligand.

Abstract

Dialkyl Tartrate as a Chiral Ligand. -(R,R)-Diisopropyl tartrate is used as a source of chirality in the inter-or intramolecular reductive aldol-type synthesis of -hydroxy esters, however, the chiral induction is rather poor. -(ISODA, M.; SATO, K.; TOKURA, Y.; TARUI, A.; OMOTE, M.; ANDO*, A.; Chem. Pharm. Bull. 62 (2014) 10, 956-961, http://dx.doi.org/10.1248/cpb.c14-00223 ; Fac. Pharm. Sci., Setsunan Univ., Hirakata, Osaka 573-0101, Japan; Eng.) -R. Staver 13-030