ChemInform Abstract: Aryl Trialkylsilyl Ketenes: Acid‐Catalyzed Synthesis from 1‐Aryl‐2‐diazo‐2‐trialkylsilylethanones and Their Conversion into 3‐Silyl‐1‐silyloxyallenes.
Abstract:Ketenes and derivatives Q 0380Aryl Trialkylsilyl Ketenes: Acid-Catalyzed Synthesis from 1-Aryl-2-diazo-2-trialkylsilylethanones and Their Conversion into 3-Silyl-1-silyloxyallenes. -A convenient method to prepare silyl ketenes of type (IV) combines silylation of aryl diazomethyl ketones and an acid-induced Wolff rearrangement of the intermediate silyl diazo ketones in one pot. The rearrangement can be catalyzed either by a proton acid such as TfOH or distinctly more slowly by the trialkylammonium salt which is… Show more
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