ChemInform Abstract: ANTHRACYCLINONES. PART 4. THE USE OF DBN OR DBU IN A NOVEL EXTENSION OF THE MARSCHALK REACTION LEADING TO HYDROXYGLYCITYLANTHRAQUINONES

Qureshi, Shireen; Shaw, G.; BURGESS, G. E.

doi:10.1002/chin.198545316

Chemischer Informationsdienst

1985

DOI: 10.1002/chin.198545316

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ChemInform Abstract: ANTHRACYCLINONES. PART 4. THE USE OF DBN OR DBU IN A NOVEL EXTENSION OF THE MARSCHALK REACTION LEADING TO HYDROXYGLYCITYLANTHRAQUINONES

Shireen Qureshi¹,

G. Shaw²,

G. E. BURGESS³

Abstract: Der Einsatz von DBN (oder DBU) bei der Umsetzung der Aldehyde (II) mit (III) ermöglicht die Darstellung von (IV) in einem neutralen nicht‐wäßrigen Medium [Ausb. an (IVa) im NaOll/HzO/MeüH/Tl‐IF‐System: 34%]; dabei tritt bei (IIc) Transacylierung zum Produkt (IVc) ein.

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ChemInform Abstract: ANTHRACYCLINONES. PART 4. THE USE OF DBN OR DBU IN A NOVEL EXTENSION OF THE MARSCHALK REACTION LEADING TO HYDROXYGLYCITYLANTHRAQUINONES

Abstract: Der Einsatz von DBN (oder DBU) bei der Umsetzung der Aldehyde (II) mit (III) ermöglicht die Darstellung von (IV) in einem neutralen nicht‐wäßrigen Medium [Ausb. an (IVa) im NaOll/HzO/MeüH/Tl‐IF‐System: 34%]; dabei tritt bei (IIc) Transacylierung zum Produkt (IVc) ein.

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