Abstract:Beim Behandeln des Di‐Li‐Addukts von 1,2‐Dicarba‐closo‐dodekaboran(12) in Äther mit einem Äquivalent (Ph3P)2NiCl2 (Ph = ‐C6H5) in Äther entsteht der Komplex (Ph3P)2NiC2B10H10, für den aufgrund von analytischen, IR‐ und NMR‐Daten eine Struktur mit o‐Bindungen zwischen dem Ni‐Atom und den beiden C‐Atomen der chelatbildenden o‐Carboran‐Einheit diskutiert wird.
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