ChemInform Abstract: An Oxidative Carbon—Carbon Bond Formation System in Cycloalkane‐Based Thermomorphic Multiphase Solution.

Abstract

Solution. -Electrolysis of phenols in the presence of unactivated alkenes using a temperature-controlled three-phase solvent system gives the desired cycloaddition products. The solvent system separates the different stages of the reaction (selective carbocation generation, C-C bond formation) and the products from each other. The formation of a thermomorphic middle layer composed of cyclohexane/ LiClO 4 / MeNO2 results in enhanced interaction between aliphatic alkenes and polar unstable cation. -(KIM, S.; NODA, S.; HAYASHI, K.; CHIBA*, K.; Org.