ChemInform Abstract: Addition Reaction of β,γ‐Unsaturated Alcohols with Divinyl Sulfoxide.

Abstract

Addition Reaction of β,γ-Unsaturated Alcohols with Divinyl Sulfoxide.-Divinyl sulfoxide (I) is coupled with the allylic alcohols (II) to give the mono-(III) or bisaddition products (IV) depending on the molar ratio of the educts. Pyrolysis of (IIIa) in the presence of KOH leads to the formation of allyl vinyl ether (V). -(KOZYREV, V. G.; VORONKOV, M. G.; ZHMYKHOVA, I. P.; CHERNYSHOVA, N. A.; Zh.