ChemInform Abstract: Access to Functionalized Bicyclo[4,3,0]nonenes via Palladium‐Catalyzed Oxidative Cyclization of 2‐Allylcyclohexyl Oximes.

Abstract

Access to Functionalized Bicyclo[4,3,0]nonenes via Palladium-Catalyzed Oxidative Cyclization of 2-Allylcyclohexyl Oximes. -Starting from the chiral title substrates the synthesis of either bicyclic hydroxyaldehydes or enones bearing aliphatic substituents can be achieved by variation of the catalytic system. -(ZHU*, J.-L.; WU, S.-T.; SHIE, J.-Y.; J. Org. Chem. 79 (2014) 8, 3623-3633, http://dx.doi.org/10.1021/jo5005422 ; Dep. Chem., Natl. Dong Hwa Univ., Shoufeng, Hualien 974, Taiwan; Eng.) -B. Voigt 45-108