Abstract:A Simple and Highly Diastereoselective One-Pot Synthesis of 1,3-Diamines.-A variety of title diamines (10 examples) with three stereogenic centers are generated in a highly diastereoselective manner (≥ 99% diastereoselectivity in all cases), using the in situ reduction of intermediately formed quaternary iminium salts.-(MERLA, B.; AREND, M.; RISCH, N.; Synlett (1997) 2, 177-178;
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