ChemInform Abstract: A Reusable FeCl3·6H2O/Cationic 2,2′‐Bipyridyl Catalytic System for the Coupling of Aryl Iodides with Thiols in Water under Aerobic Conditions.
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“…Other transition metals like Nickel, 8−10 Iron, 11,12 Cobalt, 13 and Copper, 14−23 have emerged as more attractive metal catalysts of choice. Of these, copper tops the list because it is far cheaper than Pd and also less nontoxic than Ni and Co.…”
Diol
functionalized ionic liquids (DFILs) with various anions as
a ligand have been investigated for the copper(I)-catalyzed C–S
coupling reaction. The dependence of reactivity and selectivity of
the ionic liquids on the anion was demonstrated by experimental studies
and supported by Density Functional Theory (DFT) calculations. The
interaction energies obtained from the DFT calculations showed a good
agreement with the experimental yields of the products.
“…Other transition metals like Nickel, 8−10 Iron, 11,12 Cobalt, 13 and Copper, 14−23 have emerged as more attractive metal catalysts of choice. Of these, copper tops the list because it is far cheaper than Pd and also less nontoxic than Ni and Co.…”
Diol
functionalized ionic liquids (DFILs) with various anions as
a ligand have been investigated for the copper(I)-catalyzed C–S
coupling reaction. The dependence of reactivity and selectivity of
the ionic liquids on the anion was demonstrated by experimental studies
and supported by Density Functional Theory (DFT) calculations. The
interaction energies obtained from the DFT calculations showed a good
agreement with the experimental yields of the products.
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