ChemInform Abstract: A Novel Photochemical Synthesis of Dideoxyfuranosyl Disaccharides.

Abstract

A Novel Photochemical Synthesis of Dideoxyfuranosyl Disaccharides.-Irradiation of the chiral ketone results in rearrangement to a furan-derived carbene, which is trapped by monosaccharides to yield products from OH insertion of the carbene. -(ANGELINI, M. P.; LEE-RUFF, E.; Tetrahedron Lett. 39 (1998) 48, 8783-8786; Dep. Chem., York Univ., North York, Toronto, Ont. M3J 1P3, Can.; EN)