Abstract:A Family of Rare Earth Molybdenum Bronzes: Oxides Consisting of PeriodicArrays of Interacting Magnetic Units. -The compounds LnMo 16O44 (Ln: Y, La-Lu) are synthesized from stoichiometric mixtures of Ln 2O3, Mo, and MoO3 (silica tubes, 700 C, 5 d) and characterized by powder and single crystal XRD, magnetic measurements, and DFT electronic structure calculations. All the compounds crystallize in the rhombohedral space group R3. The structure contains two types of distinct layers built from corner-sharing MoO 6… Show more
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