ChemInform Abstract: 1,2‐DITHIOL‐3‐THIONE‐4,5‐DITHIOLATE FROM CARBON DISULFIDE AND ALKALI METAL

Steimecke, Günter; SIELER, H.-J.; Kirmse, R.; Dietzsch, W.; Hoyer, Eberhard

doi:10.1002/chin.198226170

Search citation statements

Order By: Relevance

Paper Sections

Select...

Introduction1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1994

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(1 citation statement)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…3 In this work, the mass spectra of compounds 1 and 2 were studied by metastable ion analysis and collision-induced dissociation with the double aim of studying the possible isomerization of molecular ions and to provide an eficient method for isomer differentiation.…”

Section: Introductionmentioning

confidence: 99%

Differentiation and electron ionization‐induced isomerization of 4,5‐Bis(alkylthio)‐1,3‐dithiole‐2‐thiones and 1,2‐dithiole‐3‐thiones

Andreu

Gayán

Garı́n

et al. 1994

Org. Mass Spectrom.

View full text Add to dashboard Cite

The electron impact ionization mass spectra of 4,5-bis(alkylthio)-l,3dithiole-2-thiones and their 1,'tdithiole-3thione isomers were studied by accurate mass measurements and linked scans. The relative abundance of ions formed following the extrusion of S, , CS or CS, allows an unambiguous isomer differentiation. Isomerization of molecular ions was studied by means of metastable ion analysis and collision-induced dissociation. The order of reactivity was analogous to that observed in isomerization under photochemical conditions.

show abstract

Section: Introductionmentioning

confidence: 99%

Differentiation and electron ionization‐induced isomerization of 4,5‐Bis(alkylthio)‐1,3‐dithiole‐2‐thiones and 1,2‐dithiole‐3‐thiones

Andreu

Gayán

Garı́n

et al. 1994

Org. Mass Spectrom.

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: 1,2‐DITHIOL‐3‐THIONE‐4,5‐DITHIOLATE FROM CARBON DISULFIDE AND ALKALI METAL

Abstract: Das aus CS2 (I) mit Alkalimetallen und Benzoylchlorid zugängliche Bisbenzoylthio‐dithiolthion (II) wird nach alkalischer Verseifung‐durch Methyliodid (III) zu Bismethylthio‐dithiolthion (IV) alkyliert, das mit überschüssigem (III) das Trismethylthio‐dithioliumiodid (V) liefert.

Cited by 1 publication

References 1 publication

Differentiation and electron ionization‐induced isomerization of 4,5‐Bis(alkylthio)‐1,3‐dithiole‐2‐thiones and 1,2‐dithiole‐3‐thiones

Differentiation and electron ionization‐induced isomerization of 4,5‐Bis(alkylthio)‐1,3‐dithiole‐2‐thiones and 1,2‐dithiole‐3‐thiones

Contact Info

Product

Resources

About