Amorphous EuB 6 was successfully prepared having a high specific surface area (221.3 m 2 g −1 ) via the reaction between EuCl 3 and B 2 H 6 in the presence of liquid plasma in an ionic liquid environment. The material exhibits an immediate, lasting, and highly selective response toward formaldehyde at room temperature with a detection limit of 50 ppb. The good sensing performance of the amorphous EuB 6 material is attributed to the strong interaction between formaldehyde and the increased number of accessible electron-rich surface Eu sites.