Chemical synthesis and characterization of the C60-Pd polymer spherical nanoparticles

Brancewicz, Ewa; Grądzka, Emilia; Basa, Anna; Winkler, Krzysztof

doi:10.1016/j.electacta.2013.10.027

Cited by 17 publications

(26 citation statements)

References 63 publications

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“…However, the chemical syntheses allow to control size and the shape of the polymer. The chemically synthesized Pd C 60 polymer [502] forms of large cubic particles with size ranges from 20 to 80 m, which are composed of a small spherical nanoparticles 20-200 nm in diameter, as observed by TEM analyses. It is been also observed that the thermal decomposition of the composite allows to obtain Pd nanoparticles [503].…”

Section: Phmentioning

confidence: 97%

Coordination chemistry on carbon surfaces

Axet¹,

Dechy‐Cabaret²,

Durand³

et al. 2016

Coordination Chemistry Reviews

106

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Section: Phmentioning

confidence: 97%

Coordination chemistry on carbon surfaces

Axet¹,

Dechy‐Cabaret²,

Durand³

et al. 2016

Coordination Chemistry Reviews

106

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“…The formation, structure, and properties of poly-Pd n C 60 were the most intensively investigated. , The polymer is formed according to the following reaction The composition and structure of the product depend on the ratio of C 60 to the metal complex used in the synthesis. , Thermogravimetric analysis (Figure ) indicates, however, that the amount of palladium in the deposited material is higher than that in the solution used for synthesis . The results obtained for the study of composition of polymeric material as a function of concentration of polymerization precursors in growth solution is summarized in Table .…”

Section: Formation and Structure Of Two-component Polymers With C60 A...mentioning

confidence: 99%

Section: Formation and Structure Of Two-component Polymers With C60 A...mentioning

confidence: 99%

Two-Component Polymeric Materials of Fullerenes and the Transition Metal Complexes: A Bridge between Metal–Organic Frameworks and Conducting Polymers

2016

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In this review, we examined the interactions of metal complexes and metal surfaces with fullerenes. That information has been related to the formation of redox-active materials produced by electrochemical reduction of solutions of various transition metal complexes and fullerene or fullerene adducts. These redox-active polymers are strongly bound to electrode surfaces and display electrochemical activity in solutions containing only supporting electrolyte. Extensive studies of the electrochemical behavior of these films have been used to characterize their properties and structure. The process that produces these poly-Pd(n)C60 and poly-Pt(n)C60 films can also produce composite materials that consist of metal nanoparticles interspersed with the poly-Pd(n)C60 and poly-Pt(n)C60 materials. The relationship between these redox-active films and conducting metal organic framework materials has been examined. These insoluble, redox-active polymers have potential utility for the adsorption of various gases, for the construction of capacitors, for sensing, for the preparation of metal-containing heterofullerenes, and for catalysis.

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“…In the cases in which HRTEM was used to characterize the reaction products, metallic Pd NP were also observed, even at low Pd/C 60 ratio. 26,29 If a Pd 3 C 60 fulleride has indeed been produced and characterized, 25,26 when a Pd/C 60 ratio of 3 was used, it was not the only product of the reaction, and also significant amount of NP (5-20 nm) were observed. DFT calculations have suggested that both isolated atoms and weakly bonded metal aggregates may exist in equilibrium.…”

Section: Introductionmentioning

confidence: 99%