1957
DOI: 10.1021/ja01558a014
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Chemical Species Produced by Neutron Irradiation of Phosphorus Trichloride

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Cited by 7 publications
(3 citation statements)
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“…The number of possible reactions in categories a(ii) and a(iii) is very large and they are much used preparatively (36,79), but examples of type a(i) have been studied more extensively as to thermodynamics and kinetics. Type a(i) reactions form the bulk of this review.…”
Section: Intermolecular (I)mentioning
confidence: 99%
See 1 more Smart Citation
“…The number of possible reactions in categories a(ii) and a(iii) is very large and they are much used preparatively (36,79), but examples of type a(i) have been studied more extensively as to thermodynamics and kinetics. Type a(i) reactions form the bulk of this review.…”
Section: Intermolecular (I)mentioning
confidence: 99%
“…15) (hours at 230°( 89)) PCI, + POCI, ^POCI, + PCI, (Eq 16) (on catalysis (86)) *PC1, + PSCl, ^PCI, + *PSC1, (Eq. 17) (does not occur (36))…”
Section: Group Vmentioning
confidence: 99%
“…The thermal neutron capture of phosphorus in phosphorus trichloride (28,102) and in phosphoryl chloride (25,26) resulted in a large fraction of the P32 appearing as the parent compound (88% for liquid PC13, for instance) (see Table V). This occurred even for the neutron irradiation of samples of gaseous phosphorus trichloride at the vapor pressure of the liquid at room temperature.…”
Section: B Phosphorus Halidesmentioning
confidence: 99%