Chemical Reactions of β-Aminoketones

Abstract

We present fully non-linear simulations of a self-interacting scalar field in the early universe undergoing tachyonic preheating. We find that density perturbations on subhorizon scales which are amplified by tachyonic instability maintain long range correlations even during the succeeding parametric resonance, in contrast to the predictions from the standard models of preheating dominated by parametric resonance. As a result the final spectrum exhibits memory and is not universal in shape. We find that throughout the subsequent era of parametric resonance the equation of state of the universe is almost dustlike; hence the Jeans wavelength is much smaller than the horizon scale. If our 2D simulations are accurate reflections of the situation in 3D, then there are wide regions of parameter space ruled out by overproduction of black holes. It is likely however that realistic parameter values, consistent with COBE/WMAP normalization, are safely outside this black hole overproduction region.

Recent progress in the chemistry of β-aminoketones

“…Formerly, Gevorgyan et al 163 reviewed the same topic regarding the advances in the chemistry of β-aminoketones and published an update in 1985 regarding the chemical reactivity of this type of moiety. In 2008, Simplício et al 164 reviewed the amine prodrugs including the significance of β-aminoketones as the privileged motif of many drugs.…”