Chemical effects of (n, γ) nuclear reaction on (Mo6Cl8)Cl4

Fucugauchi, Luz Alicia; Millán, Sonia Patricia; Mondragón, Alexander; Solache‐Ríos, M.

doi:10.1007/bf02039737

Cited by 4 publications

(1 citation statement)

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…15,17,18 Molybdenum based nanoclusters consist of octahedral Mo 6 units bearing eight face bridging inner halides and six terminal halides in the apical positions. 19 These apical halides are labile and can be readily exchanged to other ligands to significantly improve the photochemical properties and make them attractive candidates for applications in catalysis, 20,21 radiochemistry, 22 sensors, 23 intercalation chemistry, 24 and solar concentrators. 25 In addition, switching the inner halides from chloride to iodide has also led to improvement in the photoluminescence properties of these nanoclusters.…”

mentioning

confidence: 99%

Enhanced Electroluminescence Efficiency in Metal Halide Nanocluster Based Light Emitting Diodes through Apical Halide Exchange

Kuttipillai

Yang

Chen

et al. 2018

ACS Appl. Energy Mater.

View full text Add to dashboard Cite

Metal halide nanoclusters represent an attractive class of molecular building blocks for the design of functional materials with superior optical properties that can be utilized in a range of applications. Here, we demonstrate red and near-infrared light emitting diodes with a maximum external quantum efficiency >1%, utilizing phosphorescent octahedral molybdenum iodide nanoclusters. Efficiency improvement in these devices is realized by substituting heavier ligands in the apical nanocluster position that lead to the improvement in photoluminescence and exciton formation efficiencies in the nanoclusters. These results highlight how modulation of nanocluster salts with key terminal ligands has a profound effect on photoluminescence as well as electrical injection.

show abstract