Abstract:The methods for the synthesis of protonated forms of complex manganese oxides Mg x Mn 4 O 8 •H 2 O and Ba 6 Mn 24 O 48 (1h and 2h, respectively) in the form of whisker crystals possessing tunnel crystal structures of different sizes were optimized. The microstructural features and physicochemical properties of the synthesized materials were studied. The treatment with nitric acid leads to the formation of the Mn-O-H hydroxy groups due to the insertion of protons into the structural tunnels. The protonated form… Show more
“…Luo et al 16 studied adsorptive removal of lithium by 3D-MnO 2 from wastewater and found that 3D-MnO 2 with high degree of porosity and large pores exhibited a higher adsorption capacity than 1D-MnO 2 . Kozlova et al 17 prepared complex manganese oxides with different sizes of structural tunnels, and concluded that the tunnel size was the determining factor for the sorption of heavy metal cations. In addition, Korshin et al 18 and Abdullah et al 19 found that heavy metal ions could be complexed at different adsorption sites on birnessite and a-MnO 2 using EXAFS spectroscopy.…”
“…Luo et al 16 studied adsorptive removal of lithium by 3D-MnO 2 from wastewater and found that 3D-MnO 2 with high degree of porosity and large pores exhibited a higher adsorption capacity than 1D-MnO 2 . Kozlova et al 17 prepared complex manganese oxides with different sizes of structural tunnels, and concluded that the tunnel size was the determining factor for the sorption of heavy metal cations. In addition, Korshin et al 18 and Abdullah et al 19 found that heavy metal ions could be complexed at different adsorption sites on birnessite and a-MnO 2 using EXAFS spectroscopy.…”
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