The fulvic acid from weathered coal of Gongxian (Henan Province, P.R. China) is characterized as a typical sample with the highest degree of humification. Based on the experimental results from highresolution 1 H NMR and FT-IR spectra and correct fluorescence spectra, valuable information concerning its composition and structure has been revealed and discussed. Besides, it is suggested that D 751 chelating resin (crosslinked polystyrenes with iminodiacetic acid groups, Na + form) is very effective for removing metal ions tightly complexed with fulvic and humic acids.