Chemical Analysis of Alkali Metal Tungstates and Tungsten Bronzes.

Lutz, Christian; Conroy, Lawrence E.

doi:10.1021/ac60233a041

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Procedures For Analysis Of Rubidium Tungsten Bronzes1

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1966

1979

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Cited by 10 publications

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“…Experimental. The rubidium tungsten bronzes were prepared by the electrolysis of a rubidium tungstatetungstic anhydride melt (5). These bronzes, as well as mixtures of known composition, were irradiated together with suitable standards, in the Iowa State University UTR-10 Reactor.…”

Section: Procedures For Analysis Of Rubidium Tungsten Bronzesmentioning

confidence: 99%

“…Because the properties of the bronzes vary with composition, it has been necessary to develop techniques for determining the metal to tungsten ratio, commonly known as the a>value. For most bronzes it can be assumed that the ratio of oxygen to tungsten is 3.000 (5,7).…”

mentioning

confidence: 99%

“…In these cases attempts to develop relations between composition and lattice parameter have not been successful, and it has been necessary to develop other procedures for analyzing them. Several chemical analyses have been attempted (5,7), but these methods necessitate the destruction of the samples and require considerable time because of the chemical inertness of the tungsten bronzes.…”

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confidence: 99%

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