Chemical Activation of Banana Peel Waste-Derived Biochar Using KOH and Urea for CO2 Capture

Abstract

This article describes the synthesis and characterization of porous carbon derived from waste banana peels by chemical activation with KOH or by activation KOH and urea modification. The as-synthesized samples were carefully characterized by various techniques. The prepared carbonaceous materials possess highly developed micropore and mesopore structures and high specific surface area (up to 2795 cm2/g for materials synthetized with KOH and 2718 cm2/g for activated carbons prepared with KOH and urea). A series of KOH-activated samples showed CO2 adsorption at 1 bar to 5.75 mmol/g at 0 °C and 3.74 mmol/g at 25 °C. The incorporation of nitrogen into the carbon sorbent structure increased the carbon uptake capacity of the resulting materials at 1 bar to 6.28 mmol/g and to 3.86 mmol/g at 0 °C and 25 °C, respectively. It was demonstrated that treatment with urea leads to a significant increase in nitrogen content and, consequently, CO2 adsorption, except for the material carbonized at 900 °C. At such a high temperature, almost complete decomposition of urea occurs. The results presented in this work could be used in the future for utilization of biomass such as banana peels as a low-cost adsorbent for CO2 capture, which could have a positive impact on the environment and human health protection.