Chelate ring-opening of Pd(II) triphos complexes:

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ3P,P′,P′′}chloridopalladium(II) hexafluoridophosphate

“…The corresponding complexes with both Pt II and Pd II have been previously reported as chloride and diphenyltetrachloridostannate(IV) salts (Sevillano et al, 1999a;Garcia-Seijo et al, 2001;Housecroft et al, 1990). For other group 10-triphos complexes, see: Sevillano et al (1999b); Fernadez et al (2005); Aizawa et al (2002); Bertinsson et al (1983); Autissier et al (2005); Fernandez et al (2005).…”

Different Coordination Modes of a Tripod Phosphine in Gold(I) andSilver(I) Complexes

“…18.931(6); c 35.091(12); a 78.541 (19); fl= 87.83(3); ,= 76.24(3); Vol. 9291(6) A3; Z 4; R 9.89%; parameters 645; AF max, min: 2.08, -2.82 e/A Structure determination Intensity data were collected on a Stoe Stadi-4 diffractometer equipped with an Oxford Cryosystems low-25 temperature device operating at 220 K. Crystals of 2 and 4 diffracted very weakly and so Cu-K radiation was used for data collection on account of its intensity advantage over Mo-Kc radiation, which was used for 3.…”

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ3P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate

“…The corresponding complexes with both Pt II and Pd II have been previously reported as chloride and diphenyltetrachloridostannate(IV) salts (Sevillano et al, 1999a;Garcia-Seijo et al, 2001;Housecroft et al, 1990). For other group 10-triphos complexes, see: Sevillano et al (1999b); Mü ller et al 2000; Aizawa et al (2002); Bertinsson et al (1983); Autissier et al (2005); Fernandez et al (2005); King et al (1971). Table 1 Selected bond lengths (Å ).…”