We report on a detailed study of the photoluminescence (PL) in high quality GaAs/AlGaAs quantum wells containing a two-dimensional electron gas. The 2DEG density was varied by optical depletion (with He-Ne laser illumination) in the range of n 2D = (7-3) × 10 10 cm -2 . The n 2D -dependent PL spectra were studied under a perpendicularly applied magnetic field B < 12 T at T L = 0.3 and 1.5 K. The evolution from free hole-2DEG to charged exciton PL with decreasing n 2D or with increasing magnetic field is attributed to the appearance of regions containing localized electrons as the filling factor decreases below ν = 0.4-0.3. This results in simultaneous PL of the free hole-2DEG originating from electron puddles and of charged exciton from regions with localized electrons.The remarkable transport properties of the two dimensional electron gas (2DEG) in the quantum Hall regime have stimulated an extensive investigation of the photoluminescence (PL) in modulation-doped quantum wells (MDQWs) under a perpendicularly applied magnetic field [1][2][3][4][5]. Intensity and energy oscillations of the free hole-2DEG PL lines were observed at integer and fractional filling factors ν in modulation-doped GaAs/AlGaAs heterostructures when the separation between the photoexcited valence hole and the 2DEG layer, d eh , exceeds the average electron-electron distance n 2D -1/2 (n 2D is the 2DEG density) or the magnetic lengthVarious theories predict that the PL, in this case, is a sensitive probe of the many-body interaction in the magnetized 2DEG [6][7][8].In the opposite case, d eh < L B , the Coulomb interaction of the photoexcited valence hole with the electrons affects the 2DEG properties. This is expected for MDQW's having n 2D < 10 11 cm -2 since the built-in electrical field is too weak to separate the hole from the 2D-electrons even in wide (20-30nm) MDQWs [9]. One of the most remarkable features of the low-temperature PL spectrum of MDQWs is the appearance of high-energy PL bands at filling factors ν < 1 [1]. Previously, these PL bands were attributed to the radiative recombination of the hole with fractionally charged 2DEG quisiparticles. Then, they were associated with neutral and negatively charged excitons, X 0 and X -, respectively [10, 11 and refs. there]. The X -complex consists of two electrons and a hole, and in a magnetic field, two bound states, X s --spin-singlet and X t --spin-triplet, can be formed. The lowest energy X t -is a "dark" state [12], and it can emit light either if it is localized or it is scattered by disorder or by 2D-electrons [11,12]. Recently, a splitting of the high-energy, broad PL band into two PL lines was observed at ν < 1/3, and these lines